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Fluid Properties
Published in W. M. Haynes, David R. Lide, Thomas J. Bruno, CRC Handbook of Chemistry and Physics, 2016
W. M. Haynes, David R. Lide, Thomas J. Bruno
Molecular Formula Comp. 1 Comp. 2 C8H16O2 C8H18 C8H18 C8H18O C8H18O C8H19N C9H10 C9H12 C9H12O C9H20 C9H20O C10H22 C10H22O C12H27N C2H6O C3H6O C3H8O C3H8O C4H6O C4H6O C4H8O C4H8O2 C4H10O C4H10O C5H10O CH4O CH4O C2H6O C3H6O C3H6O2 C3H8O C4H6O C6H12 C6H14 C3H5Cl C2H6O C2H4Cl2 C5H10O2 C8H10 C2H6O C3H7Br C4H8O2 C5H10 C7H14 C7H16 C8H18 C9H20 C10H22 C11H24 C12H26 C2HBrClF3 Name Butyl butanoate Octane 2,2,4-Trimethylpentane Dibutyl ether 1-Octanol Dibutylamine Isopropenylbenzene Isopropylbenzene 2-Phenyl-2-propanol Nonane 1-Nonanol Decane 1-Decanol Tributylamine Tetrachloromethane Ethanol Acetone 1-Propanol 2-Propanol 2-Butenal 2-Methylpropenal 2-Butanone Ethyl acetate 1-Butanol 2-Methyl-1-propanol 2-Methyl-3-buten-2-ol Carbon disulfide Methanol Trichloromethane Methanol Ethanol Acetone Methyl acetate 2-Propanol 2-Butenal 2-Methyl-1-pentene Hexane Hydrogen cyanide 3-Chloropropene Dichloromethane Ethanol Formic acid 1,2-Dichloroethane Butyl formate m-Xylene Nitromethane Ethanol 1-Bromopropane 1,4-Dioxane 2-Methyl-2-butene Methylcyclohexane Heptane Octane Nonane Decane Undecane Dodecane Methanol 2-Bromo-2-chloro-1,1,1-trifluoroethane
Oxidations of aromatic sulfides promoted by the phthalimide N-oxyl radical (PINO)
Published in Journal of Sulfur Chemistry, 2023
Marika Di Berto Mancini, Alessandro Tabussi, Marianna Bernardini, Osvaldo Lanzalunga
Product analyses: A solution of NHPI (1 × 10−4 mol in CH3CN) was added to a solution of PhI(OAc)2 (1 × 10−4 mol in CH3CN). Then, a solution of substrate (2 × 10−4 mol in CH3CN) was added. The mixture was vigorously stirred at −30°C, to avoid the direct oxidation of sulfides by the oxidant PhI(OAc)2, for 5 min under air. After the addition of a solution of sodium metabisulfite to quench the reaction, and the internal standard (nitrobenzene or bibenzyl), the reaction mixture was filtered over a short pad of SiO2 and eluted with AcOEt. The crude mixture was directly analyzed by GC. For 1H NMR analysis, after filtration, the solvent was dried by reduced pressure. Blank experiments were carried out under the same reaction conditions reported above but in the absence of NHPI. Quantitative product analysis was carried out by comparison with authentic specimens: aryl methyl sulfoxides, benzaldehydes, benzyl alcohol, acetophenone, 1-phenylethyl alcohol, benzophenone, diphenylmethanol, 2-phenyl-2-propanol and α-methyl styrene were commercially available. Benzyl phenyl sulfoxides, 1-phenylethyl phenyl sulfoxide, 2-phenyl-2-propyl phenyl sulfoxide and diphenylmethyl phenyl sulfoxide were prepared by oxidation of the corresponding sulfides with sodium periodate according to a literature method [19]. Spectral characterization was in accordance with literature data [20–22].