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Single molecule switch devices: A minireview
Published in Instrumentation Science & Technology, 2020
Yuanjing Li, Ke Xu, Xueyang Sun
In the process of using the break-junction technique, the adsorbed molecule can connect the tip to the surface electrode through a connector at both ends of the molecule. Common break-junction techniques include scanning tunneling microscope break-junction (STM-BJ) and mechanically controllable break-junction (MCBJ).[15–17] STM-BJ technology forms a single-molecule circuit between two electrodes by “tapping” or current stretching. Under certain external circumstances, the STM tip may be brought into and out of contact with the substrate. During the contact process, molecules may connect the tip and surface electrodes. When the STM tip is pulled away from the surface, a plateau appears in the trajectory of current and distance.[18] The MCBJ approach provides a continuously adjustable gap size between two tip-shaped electrodes with impressive mechanical stability for characterizing individual molecules.[19]