Triethyl phosphite

Physical Constants of Organic Compounds

Published in W. M. Haynes, David R. Lide, Thomas J. Bruno, CRC Handbook of Chemistry and Physics, 2016

W. M. Haynes, David R. Lide, Thomas J. Bruno

Ethanol, 2,2'-[1,2-ethanediylbis(oxy)]bis-, dinitrate 10361 Triethylene glycol monoethyl 2-[2-(2-Ethoxyethoxy)ethoxy]ether ethanol 10362 Triethylenephosphoramide Tris(1-aziridinyl)phosphine, oxide 10363 Triethylenethiophosphoramide Thiotepa 10364 1,3,5-Triethylhexahydro-1,3,5triazine 10365 Triethyl phosphate Ethyl phosphate 10366 Triethylphosphine 10367 Triethylphosphine oxide 10368 Triethylphosphine sulfide 10369 Triethyl phosphite

Synthesis, X-ray crystal structures, and electrochemistry of two diiron ethane-1,2-dithiolate complexes containing tris(4-trifluoromethylphenyl)phosphine or triethyl phosphite

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Published in Inorganic and Nano-Metal Chemistry, 2022

Fei-Yan Chen, Ling-Hui Wang, Wen-Jing Tian, Xu-Feng Liu, Yu-Long Li, Xing-Hai Liu, Zhong-Qing Jiang

In summary, we have presented the synthesis of two diiron ethane-1,2-dithiolate complexes by carbonyl substitution of the hexacarbonyl complex with a phosphine ligand tris(4-trifluoromethylphenyl)phosphine or a phosphite ligand triethyl phosphite. Both complexes have been characterized by elemental analysis and various spectroscopic techniques. In addition, X-ray crystallographic studies revealed that they contain a butterfly diiron ethane-1,2-dithiolate cluster with five terminal carbonyls and an apically-coordinated phosphine or phosphite ligand. Electrochemical studies showed that both complexes can catalyze the reduction of protons to H2 in the presence of HOAc.

Triethyl phosphite

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Physical Constants of Organic Compounds

Synthesis, X-ray crystal structures, and electrochemistry of two diiron ethane-1,2-dithiolate complexes containing tris(4-trifluoromethylphenyl)phosphine or triethyl phosphite