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Hydrochloric acid regeneration in hydrometallurgical processes: a review
Published in Mineral Processing and Extractive Metallurgy, 2018
Caitlyn McKinley, Ahmad Ghahreman
Pyrohydrolysis is the only true form of hydrochloric acid regeneration that has been commercialised. Beginning from relatively simple chloride brine, pyrohydrolysis uses a fluidised bed or a spray roaster to remove the water units from the solution to produce a metal oxide and hydrochloric acid as per the following reaction:Pyrohydrolysis is a versatile process, and depending on the operating conditions used, in particular the temperature, one can control the metal chlorides targeted to selectively hydrolyse only certain metal chlorides (de Bakker 2011). Theoretically, pyrohydrolysis may be used to hydrolyse any metal chloride to its metal oxides; however, only three metals, magnesium, ferrous and nickel, have been implemented in an industrial setting.