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Inverse coordination chemistry: oxocarbons, other polyoxo carbocyclic molecules and oxygen heterocycles as coordination centers. Topology and systematization
Published in Journal of Coordination Chemistry, 2020
Ionel Haiduc
The presence of adjacent functional groups, which affords the formation of chelate rings fused with the benzene ring, favors the formation of inverse coordination complexes centered on a benzene-1,3,5-triolato core, creating a tris(bidentate) chelating topology. Illustrative examples are the triacetyl derivative [(µ-C6H3O3(COMe)3 {Cu(chel)}3]3+ chel = N(CH2CH2NH2)(CH2CH2OH)2(63) [55(a)] and carbohydrazonato derivative [(µ-C6H3O3R3(MoO2)3(MeOH)2(H2O)]0 R = CMeN = NCMeO (64) [55(b)] (Scheme 25). More inverse coordination complexes with functionalized benzene-1,3,5-triolato centroligands and chromium [56(a)], manganese [56(b-e)], iron [56(a,f,g)], cobalt [56(h)], nickel [56(i-p)], copper [56(q-v)] and aluminium [56(w)] as coordinated metals with rather intricate peripheral ligands have been reported.