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The Synergistic Copper Process concept
Published in Mineral Processing and Extractive Metallurgy, 2018
William Hawker, James Vaughan, Evgueni Jak, Peter C. Hayes
Copper can be precipitated from the leach solution in a number of ways to form an intermediate low-iron, copper-containing solid product. The most applicable to this discussion would be to precipitate the copper as a copper oxide-type solid. In practice, the precipitation of copper from sulphate solutions can be achieved by the cooling of saturated solutions, or by pH adjustment resulting in the formation of a basic copper sulphate solid, most likely brochantite (CuSO4.3Cu(OH)2), or its hydrated form, posnjakite (CuSO4.3Cu(OH)2.H2O) (Hawker 2015). The precipitation of the copper as an oxide or hydroxide through changing the pH requires only relatively cheap precipitation reagents, such as limestone. The process conditions required to produce the precipitated copper product from aqueous sulphate solutions at 25°C have recently been established and are summarised in Figure 6.