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m-Aminophenol
Published in John R. Kosak, Thomas A. Johnson, Catalysis of Organic Reactions, 2020
The hydrogenation of other aromatic diamines was also examined to determine the generality of the reaction. Under the standard conditions of 60°C and a 2:1 acetic acid: MPD ratio, o-phenylenediamine and p-phenylenediamine yielded only starting material.
Physical Constants of Organic Compounds
Published in W. M. Haynes, David R. Lide, Thomas J. Bruno, CRC Handbook of Chemistry and Physics, 2016
W. M. Haynes, David R. Lide, Thomas J. Bruno
C8H10N2O C16H14O3 C8H7N C8H7ClO C6H7AsO3 C6H7BO2 C10H12O2 C10H14O C7H6O3 C7H7NS C7H6OS C7H9ClN2 o-Phenylenediamine m-Phenylenediamine p-Phenylenediamine C6H8N2 C6H8N2 C6H8N2 C6H10Cl2N2 C6H10Cl2N2 C6H10Cl2N2 Phthaloyl chloride C8H4Cl2O2
Polymers
Published in Bryan Ellis, Ray Smith, Polymers, 2008
Synonyms: 2,2 -Bis(3,4-dicarboxyphenyl)hexafluoropropane dia- nhydride-co-m-phenylenediamine-co-p-phenylenediamine. Poly(5,5'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis-1,3- isobenzofurandione-co-m-phenylenediamine-co-p-phenylenediamine. Poly(4,4'-(hexafluoroisopropylidene)bis(phthalic anhydride)-co- m-phenylenediamine-co-p-phenylenediamine). Poly[(1,3-dihydro- 1,3-dioxo-2H-isoindole-2,5-diyl)[2,2,2-trifluoro-1-(trifluoromethy- l)ethylidene](1,3-dihydro-1,3-dioxo-2H-isoindole-5,2-diyl)pheny- lene]
Metallonucleases encompassing curcumin, 2-aminobenzothiazole and o-phenylenediamine: a search for new metallonucleases
Published in Inorganic and Nano-Metal Chemistry, 2021
Natarajan Raman, Thiravidamani Chandrasekar
Two important properties of 2-aminobenzothiazole molecule such as the tautomerism of its delocalized dienyl system N–C–N and the fact that a C = N–H imine group is at the same time a base and a very reactive acid[40] which make it a good candidate for coordination studies. The derivatives of benzothiazole have enormous application in the field of medicine and therapeutic fields. A few of them have been investigated as anti-inflammatory, antitumor drug, Parkinson's disease and antihistaminic. The thiazole derivatives also play a vital role in the treatment against cancer and antibacterial agents. Their structural unit identified in antioxidant, anti-inflammatory, herbicides, antibiotics, thermoplastic polymers[41] and flavoring and odor agents and responsible for the bioluminescence of fire flies.[42]o-Phenylenediamine has received more attention due to its synthetic flexibility, rich coordination chemistry and application in catalysis, medicine as antibiotics and anti-inflammatory agent and in the industry as anticorrosion. Related unsymmetrical Schiff bases have received less attention. The unsymmetrical Schiff bases of 1,2-diamines may be of more practical importance due to the presence of the different reactive centers located in the compounds. Unsymmetrical Schiff bases are important in understanding the process of metal binding in metalloproteins and metalloenzymes in the body.[43–47] Herein, we have tried to synthesize four metal complexes using the curcumin based Schiff base and o-phenylenediamine which are found to be good metallonucleases.