Sediment-associated organopollutants, metals and nutrients in the Nechako River, British Columbia: a current study with a synthesis of historical data
Published in Canadian Water Resources Journal / Revue canadienne des ressources hydriques, 2019
Philip N. Owens, David J. Gateuille, Ellen L. Petticrew, Barry P. Booth, Todd D. French
Phenoxy acid herbicide (triclopyr, bromoxynil, clopyralid, 2,4-D, dicamba, 2,4-DB, 2,4-DP [dichlorprop], dinoseb, MCPA, MCPB, mecoprop, picloram, 2,4,5-T, and 2,4,5-TP) determinations in bottom sediment were done by ALS Environmental Ltd (Burnaby, BC) in collaboration with AXYS. Per ALS Method L1856769, 5-g samples were mixed with methanol, acidified and extracted with toluene; derivatized extracts were analyzed by capillary column GC-MS. Samples were run in batches of 20; each batch included a method blank based on Baked Ottawa Sand, a laboratory control and duplicate, phenoxy acid herbicide surrogates, a sample split duplicate, and a phenoxy acid herbicide matrix spike.