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Thermochemistry, Electrochemistry, and Solution Chemistry
Published in W. M. Haynes, David R. Lide, Thomas J. Bruno, CRC Handbook of Chemistry and Physics, 2016
W. M. Haynes, David R. Lide, Thomas J. Bruno
Anisole Anthracene Anthracene Anthracene 9,10-Anthracenedione Apomorphine -Arginine -Ascorbic acid -Ascorbic acid -Asparagine -Aspartic acid -Aspartic acid -Aspartic acid Atrazine Atropine Azinphos-methyl trans-Azobenzene Bayleton Bendiocarb Bentazon Benzaldehyde Benzamide Benz[a]anthracene Benz[a]anthracene Benzene Benzene Benzene Benzene Benzene Benzene Benzene Benzeneacetic acid 1,2-Benzenediamine 1,3-Benzenediamine 1,4-Benzenediamine 1,2-Benzenedicarboxamide Benzeneethanol Benzenehexacarboxylic acid Benzenepentacarboxylic acid Benzenepentacarboxylic acid Benzenepentacarboxylic acid 1,2,3,4-Benzenetetracarboxylic acid 1,2,3,4-Benzenetetracarboxylic acid 1,2,3,4-Benzenetetracarboxylic acid 1,2,3,5-Benzenetetracarboxylic acid 1,2,3,5-Benzenetetracarboxylic acid 1,2,3,5-Benzenetetracarboxylic acid 1,2,4,5-Benzenetetracarboxylic acid 1,2,4,5-Benzenetetracarboxylic acid 1,2,4,5-Benzenetetracarboxylic acid 1,2,3-Benzenetricarboxylic acid 1,2,3-Benzenetricarboxylic acid 1,2,3-Benzenetricarboxylic acid 1,2,4-Benzenetricarboxylic acid 1,2,4-Benzenetricarboxylic acid 1,2,4-Benzenetricarboxylic acid 1,3,5-Benzenetricarboxylic acid 1,3,5-Benzenetricarboxylic acid 1,3,5-Benzenetricarboxylic acid 1,2,3-Benzenetriol
Enhanced selective copper precipitation by mechanochemically activated benzene tricarboxylic acid
Published in Environmental Technology, 2023
Qing Shi, Shanshan Yan, Chao Wang, Chaocheng Zeng, Huimin Hu, Mengfei Chen, Min Chen, Qiwu Zhang
Benzene tricarboxylic acid (1,3,5-benzenetricarboxylic acid, BTC) has been widely studied to synthesise various metal-organic frameworks (MOFs), of which copper can form Cu3(BTC)2 framework with BTC, usually by a hydrothermal method in an alkaline environment [22,23], to be used as functional materials due to its porous structure [24–26] to demonstrate improved absorption performance [27,28]. As to a direct interaction between benzene tricarboxylic acid and heavy metals, it has been found that benzene tricarboxylic acid can adsorb complex metal ions under hydrothermal conditions [29] or by electrochemical means [30,31]. However, no reports are available on a direct use of BTC to deal with copper-containing waste solution from a stance of environmental purification, probably due to a poor reactivity of BTC.
Gas sorption and luminescence properties of activated forms of a cd(II)-coordination polymer
Published in Journal of Coordination Chemistry, 2021
Lovely Tyagi, Ravindra Singh, Prem Lama, Kafeel Ahmad Siddiqui
The rigid O-donor 1,3,5-benzenetricarboxylic acid (H3BTC) is common since its three carboxylate groups on the benzene ring can be used as a short and long bridge between metal centers resulting in variety structures [32–34]. The N-donor 1,3-bis(4-pyridyl)propane (BPP) is a flexible ligand, which may show different conformations (anti-anti, gauche-gauche, anti-gauche, gauche-gauche') due to methylene spacer present between two pyridyl rings, allowing the pyridyl group to bend and rotate freely to conform to the coordination geometries of metal ions [35]. As a part of our ongoing work on Cd-BTC/Cd-BPP coordination polymer [7, 32], here we report the thermogravimetric analysis, gas sorption, and luminescence properties of different activated forms of {[Cd(HBTC)(BPP)]·1.5DMF·2H2O}n (1).
A new stable porous Pr-organic framework constructed by multi-iodine-substituted aromatic polycarboxylates: Synthesis, characterization, and selective adsorption of dyes
Published in Journal of Coordination Chemistry, 2019
Ying Sun, Feng Ying Bai, Xue Min Wang, Yu Wang, Li Xian Sun, Yong Heng Xing
Triangle polycarboxylic acid ligands have multiple carboxylic acid groups, many coordination sites and diverse coordination modes. Moreover, they can be combined with rare earth metals to form large-hole functional crystal materials and have good potential application value in adsorption, luminescence and other fields [26, 27]. Herein, 2,4,6-triiodo-1,3,5-benzenetricarboxylic acid and Pr3+ ion produced a 3D cage compound, {Pr(TIBTC)(DMF)3}n (1) (H3TIBTC = 2,4,6-triiodo-1,3,5-benzene tricarboxylic acid). Friscic et al. introduced a halogen atom into the compound and reassembled it to form a halogen bond to increase the dimension of the compound [28]. They used R in the formula as a substituent with iodophenyl and bromophenyl, thereby introducing a halogen atom to form a halogen bond. At the same time, a series of compounds with 2D or 3D structure were synthesized. The role of I···I and Br···Br play an important role in the construction of these stacked structures [29].