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If a sample contains a single, known compound, the PID may be calibrated with a gas standard and used to determine the concentration of the sample gas based on a response factor. The response factor is dependent on both the sample and the calibration gas.
Quantitative measurement of formaldehyde formed in combustion processes using gas chromatography analytical approach
For liquid samples, the response factor for the (i) species is defined as the ratio of the relevant peak area (Ai) to its mole fraction (χi). So, the response factors and respectively for formaldehyde and acetaldehyde, are the following: